Journal of the American Chemical Society

1、[ASAP] Crystal Structure and C–H Bond-Cleaving Reactivity of a Mononuclear Co^IV–Dinitrate Complex

Yubin M. Kwon†, Yuri Lee‡, Garrett E. Evenson†, Timothy A. Jackson*‡, and Dong Wang*†

2、[ASAP] Boramidine: A Versatile Structural Motif for the Design of Fluorescent Heterocycles

Yury Lebedev†, Chirag Apte†, Susan Cheng†, Cyrille Lavigne‡, Alan Lough†, Ala´n Aspuru-Guzik*‡§??, Dwight S. Seferos*†#, and Andrei K. Yudin*†

3、[ASAP] The Rise of the Dynamic Crystals

Panc?e Naumov*†‡, Durga Prasad Karothu†?, Ejaz Ahmed†?, Luca Catalano†§?, Patrick Commins†?, Jad Mahmoud Halabi†?, Marieh B. Al-Handawi†?, and Liang Li†?

4、[ASAP] Gold Catalyzed Decarboxylative Cross-Coupling of Iodoarenes

Ryan A. Daley†, Aaron S. Morrenzin‡, Sharon R. Neufeldt*‡, and Joseph J. Topczewski*†

5、[ASAP] Alternating Cascade Metathesis Polymerization of Enynes and Cyclic Enol Ethers with Active Ruthenium Fischer Carbenes

Xuelin Sui, Tianqi Zhang, Alec B. Pabarue, Liangbing Fu, and Will R. Gutekunst*

6、[ASAP] On-Surface Synthesis of Oligo(indenoindene)

Marco Di Giovannantonio*†, Qiang Chen‡, Jose´ I. Urgel†, Pascal Ruffieux†, Carlo A. Pignedoli†, Klaus Mu¨llen*‡§, Akimitsu Narita*‡?, and Roman Fasel*†?

7、[ASAP] Photochemical Unmasking of Polyyne Rotaxanes

Steffen L. Woltering, Przemyslaw Gawel, Kirsten E. Christensen, Amber L. Thompson, and Harry L. Anderson*

8、[ASAP] Immobilization of Phosphatidylinositides Revealed by Bilayer Leaflet Decoupling

Simou Sun†, Chang Liu†, Danixa Rodriguez Melendez§, Tinglu Yang†, and Paul S. Cremer*†‡

9、[ASAP] From Hexaphenylbenzene to 1,2,3,4,5,6-Hexacyclohexylcyclohexane

Marcel Dillenburger†?, Zijie Qiu*?†, Cheng-Wei Ju†‡, Beate Mu¨ller†, Svenja Morsbach†, Dieter Schollmeyer§, Akimitsu Narita*†, and Klaus Mu¨llen*†

10、[ASAP] C–H/C–C Functionalization Approach to N-Fused Heterocycles from Saturated Azacycles

Jin Su Ham||, Bohyun Park‡†, Mina Son‡†, Jose B. Roque||, Justin Jurczyk||, Charles S. Yeung*#, Mu-Hyun Baik*†‡, and Richmond Sarpong*||

11、[ASAP] A Super-Oxidized Radical Cationic Icosahedral Boron Cluster

Julia M. Stauber†, Josef Schwan‡, Xinglong Zhang‡, Jonathan C. Axtell†§, Dahee Jung†, Brendon J. McNicholas‡, Paul H. Oyala‡, Andrew J. Martinolich‡, Jay R. Winkler‡, Kimberly A. See‡, Thomas F. Miller, III*‡, Harry B. Gray*‡, and Alexander M. Spokoyny*†

12、[ASAP] Plasmon-Driven Chemistry in Ferri-/Ferrocyanide Gold Nanoparticle Oligomers: A SERS Study

Yue Qi, Vitor Brasiliense, Tyler W. Ueltschi, Ji Eun Park, Michael R. Wasielewski*, George C. Schatz*, and Richard P. Van Duyne†

13、[ASAP] Two-Photon Fluorescence Microscopy at Extremely Low Excitation Intensity: The Power of Quantum Correlations

Oleg Varnavski† and Theodore Goodson III*†‡

14、[ASAP] Helical Nanographenes Embedded with Contiguous Azulene Units

Naoki Ogawa, Yousuke Yamaoka, Hiroshi Takikawa, Ken-ichi Yamada†, and Kiyosei Takasu*

15、[ASAP] Interlayer Shifting in Two-Dimensional Covalent Organic Frameworks

Chengjun Kang†, Zhaoqiang Zhang†, Vanessa Wee†, Adam K. Usadi‡, David C. Calabro‡, Lisa Saunders Baugh‡, Shun Wang†, Yuxiang Wang†, and Dan Zhao*†

16、[ASAP] Mechanistic Insights into Photocatalyzed H₂ Dissociation on Au Clusters

Qisheng Wu†, Linsen Zhou†, George C. Schatz¶, Yu Zhang*‡, and Hua Guo*†

17、[ASAP] Real-Space Imaging of a Single-Molecule Monoradical Reaction

Shaotang Song†‡#, Na Guo?#, Xinzhe Li†, Guangwu Li†, Yohei Haketa§, Mykola Telychko†?, Jie Su†?, Pin Lyu†, Zhizhan Qiu†, Hanyan Fang†, Xinnan Peng†, Jing Li†, Xinbang Wu†, Ying Li‡, Chenliang Su‡, Ming Joo Koh†, Jishan Wu†, Hiromitsu Maeda§, Chun Zhang†??, and Jiong Lu*†?

18、[ASAP] Two-Dimensional Carbon-Rich Conjugated Frameworks for Electrochemical Energy Applications

Minghao Yu‡, Renhao Dong‡, and Xinliang Feng*

19、[ASAP] Allosteric Cooperativity and Template-Directed Synthesis with Stacked Ligands in Porphyrin Nanorings

Pernille S. Bols, Michel Rickhaus‡, Lara Tejerina‡, Henrik Gotfredsen, Kristina Eriksen, Michael Jirasek, and Harry L. Anderson*

20、[ASAP] Regioselective Synthesis and Characterization of Tris- and Tetra-Prato Adducts of M₃N@C₈₀ (M = Y, Gd)

Olesya Semivrazhskaya†, Safwan Aroua†, Maxim Yulikov§, Adrian Romero-Rivera?, Steven Stevenson‡, Marc Garcia-Borra`s?, Si´lvia Osuna*??, and Yoko Yamakoshi*†

21、[ASAP] Coordination Environment-Controlled Photoinduced Electron Transfer Quenching in Luminescent Europium Complexes

Daniel Kovacs‡, Emilie Mathieu‡, Salauat R. Kiraev‡, Jordann A. L. Wells, Ellen Demeyere, Agne`s Sipos, and K. Eszter Borbas*

22、[ASAP] Enantioselective Type II Cycloaddition of Alkynes via C–C Activation of Cyclobutanones: Rapid and Asymmetric Construction of [3.3.1] Bridged Bicycles

Si-Hua Hou, Xuan Yu†, Rui Zhang†, Lin Deng§, Mengxi Zhang, Adriana Y. Prichina, and Guangbin Dong*

23、[ASAP] Intramolecular Hydrogen Bonding-Based Topology Regulation of Two-Dimensional Covalent Organic Frameworks

Yongwu Peng†‡#, Liuxiao Li†#, Chongzhi Zhu‡, Bo Chen†, Meiting Zhao†, Zhicheng Zhang†, Zhuangchai Lai†, Xiao Zhang†, Chaoliang Tan§, Yu Han?, Yihan Zhu*‡, and Hua Zhang*§?

24、[ASAP] Interception of the Bycroft–Gowland Intermediate in the Enzymatic Macrocyclization of Thiopeptides

Jonathan W. Bogart†‡§, Nicholas J. Kramer†§, Aneta Turlik?, Rachel M. Bleich†, Daniel S. Catlin?, Frank C. Schroeder#, Satish K. Nair??, R. Thomas Williamson?, K. N. Houk?, and Albert A. Bowers*†?

25、[ASAP] Ni-Catalyzed Traceless, Directed C3-Selective C–H Borylation of Indoles

Ya-Ming Tian†, Xiao-Ning Guo*†, Zhu Wu†, Alexandra Friedrich†, Stephen A. Westcott‡, Holger Braunschweig†, Udo Radius*†, and Todd B. Marder*†

26、[ASAP] Highly Distorted Chiral Two-Dimensional Tin Iodide Perovskites for Spin Polarized Charge Transport

Haipeng Lu†, Chuanxiao Xiao†, Ruyi Song‡, Tianyang Li‡, Annalise E. Maughan†, Andrew Levin†, Roman Brunecky§, Joseph J. Berry†, David B. Mitzi‡, Volker Blum‡, and Matthew C. Beard*†

27、[ASAP] Convergent Total Synthesis of Hikizimycin Enabled by Intermolecular Radical Addition to Aldehyde

Haruka Fujino†, Takumi Fukuda†, Masanori Nagatomo, and Masayuki Inoue*

28、[ASAP] 2D-Covalent Organic Frameworks with Interlayer Hydrogen Bonding Oriented through Designed Nonplanarity

Sampath B. Alahakoon†, Kui Tan‡, Haardik Pandey§, Shashini D. Diwakara†, Gregory T. McCandless†, Daniel I. Grinffiel†, Alejandra Durand-Silva†, Timo Thonhauser§, and Ronald A. Smaldone*‡†

29、[ASAP] Manno-<italic toggle="yes">epi</italic>-cyclophellitols Enable Activity-Based Protein Profiling of Human a-Mannosidases and Discovery of New Golgi Mannosidase II Inhibitors

Zachary Armstrong†, Chi-Lin Kuo‡, Danie¨l Lahav‡, Bing Liu‡, Rachel Johnson†, Thomas J. M. Beenakker‡, Casper de Boer‡, Chung-Sing Wong‡, Erwin R. van Rijssel‡, Marjoke F. Debets‡, Bogdan I. Florea‡, Colin Hissink‡, Rolf G. Boot‡, Paul P. Geurink§, Huib Ovaa§?, Mario van der Stelt‡, Gijsbert M. van der Marel‡, Jeroen D. C. Code´e‡, Johannes M. F. G. Aerts‡, Liang Wu†?, Herman S. Overkleeft*‡, and Gideon J. Davies*†

30、[ASAP] Visible Light Mediated Bidirectional Control over Carbonic Anhydrase Activity in Cells and <italic toggle="yes">in Vivo</italic> Using Azobenzenesulfonamides

Kanchan Aggarwal†, Timothy P. Kuka‡, Mandira Banik†, Brenda P. Medellin‡, Chinh Q. Ngo†, Da Xie†, Yohaan Fernandes‡§, Tyler L. Dangerfield‡, Elva Ye†, Bailey Bouley†, Kenneth A. Johnson‡, Yan Jessie Zhang‡, Johann K. Eberhart‡§, and Emily L. Que*†

31、[ASAP] Interconversions between Uranium Mono-metallofullerenes: Mechanistic Implications and Role of Asymmetric Cages

Wenting Cai§, Janet Alvarado§, Alejandro Metta-Magan~a§, Ning Chen?, and Luis Echegoyen*§

32、[ASAP] Revealing Kinetics of Two-Electron Oxygen Reduction Reaction at Single-Molecule Level

Yi Xiao†‡, Jaeyoung Hong§?, Xiao Wang§?, Tao Chen?, Taeghwan Hyeon*§?, and Weilin Xu*†‡

33、[ASAP] Direct Imaging of Correlated Defect Nanodomains in a Metal–Organic Framework

Duncan N. Johnstone*†, Francesca C. N. Firth‡, Clare P. Grey‡, Paul A. Midgley†, Matthew J. Cliffe§, and Sean M. Collins*†?

34、[ASAP] Silver-Catalyzed Enantioselective Propargylic C–H Bond Amination through Rational Ligand Design

Minsoo Ju, Emily E. Zerull, Jessica M. Roberts, Minxue Huang, Ilia A. Guzei, and Jennifer M. Schomaker*

35、[ASAP] Self-Assembly of a Chiral Cubic Three-Connected Net from the High Symmetry Molecules C₆₀ and SnI₄

Daniel B. Straus* and Robert J. Cava*

36、[ASAP] Allenes for Versatile Iron-Catalyzed C–H Activation by Weak O-Coordination: Mechanistic Insights by Kinetics, Intermediate Isolation, and Computation

Antonis M. Messinis†#, Lars H. Finger†#, Lianrui Hu†, and Lutz Ackermann*†‡

37、[ASAP] Operando Identification of the Chemical and Structural Origin of Li-Ion Battery Aging at Near-Ambient Temperature

Min-Seob Kim†‡§, Byoung-Hoon Lee†‡§, Jae-Hyuk Park†‡§, Hyeon Seok Lee†‡, Wytse Hooch Antink†‡, Euiyeon Jung†‡, Jiheon Kim†‡, Tae Yong Yoo†‡, Chan Woo Lee†‡, Chi-Yeong Ahn†‡, Seok Mun Kang†‡, Jinsol Bok†‡, Wonjae Ko†‡, Xiao Wang†‡, Sung-Pyo Cho?, Seung-Ho Yu*?, Taeghwan Hyeon*†‡, and Yung-Eun Sung*†‡

38、[ASAP] Synthesis of Cyclo[18]carbon via Debromination of C₁₈Br₆

Lorel M. Scriven†?, Katharina Kaiser‡?, Fabian Schulz‡§, Alistair J. Sterling†, Steffen L. Woltering†, Przemyslaw Gawel†, Kirsten E. Christensen†, Harry L. Anderson*†, and Leo Gross*‡

39、[ASAP] Metal-Assisted and Solvent-Mediated Synthesis of Two-Dimensional Triazine Structures on Gram Scale

Abbas Faghani†, Mohammad Fardin Gholami‡, Matthias Trunk§, Johannes Mu¨ller‡, Pradip Pachfule§, Sarah Vogl§, Ievgen Donskyi†?, Mingjun Li†?, Philip Nickl†?, Jingjing Shao†, Michael R. S. Huang‡, Wolfgang E. S. Unger?, Raul Arenal???, Christoph T. Koch‡, Beate Paulus†, Ju¨rgen P. Rabe‡, Arne Thomas*§, Rainer Haag†, and Mohsen Adeli*†?

40、[ASAP] Regulating Photochemical Selectivity with Temperature: Isobutanol on TiO₂(110)

Carla Courtois¶$, Constantin A. Walenta§$, Martin Tschurl¶, Ueli Heiz¶, and Cynthia M. Friend*§

41、[ASAP] The Cyclopropane Ring as a Reporter of Radical Leaving-Group Reactivity for Ni-Catalyzed C(sp³)–O Arylation

L. Reginald Mills†, John J. Monteith†, Gabriel dos Passos Gomes†‡, Ala´n Aspuru-Guzik†‡§?, and Sophie A. L. Rousseaux*†

42、[ASAP] Intermolecular Allene Functionalization by Silver-Nitrene Catalysis

Manuel R. Rodri´guez†, Mari´a Besora§, Francisco Molina†, Feliu Maseras*‡, M. Mar Di´az-Requejo*†, and Pedro J. Pe´rez*†

43、[ASAP] Controlling the Self-Assembly of New Metastable Tin Vanadium Selenides Using Composition and Nanoarchitecture of Precursors

Dmitri Leo Mesoza Cordova†, Taryn Mieko Kam†, Renae N. Gannon†, Ping Lu‡, and David C. Johnson*†

44、[ASAP] Synthesis and Biological Evaluation of Shishijimicin A-Type Linker-Drugs and Antibody–Drug Conjugates

K. C. Nicolaou*†, Ruofan Li†?, Qifeng Chen†?, Zhaoyong Lu†, Emmanuel N. Pitsinos†‡, Alexander Schammel§?, Baiwei Lin§?, Christine Gu§, Hetal Sarvaiya§, Robert Tchelepi§?, Amanda Valdiosera§, Justin Clubb§?, Nicole Barbour§?, Vikram Sisodiya§?, Joseph Sandoval§?, Christina Lee§, Monette Aujay§?, and Julia Gavrilyuk§

45、[ASAP] Spotlights on Recent <italic toggle="yes">JACS</italic> Publications

ACS Contributing Correspondents

46、[ASAP] Specific Isotope-Responsive Breathing Transition in Flexible Metal–Organic Frameworks

Jin Yeong Kim†¶+, Jaewoo Park‡+, Junsu Ha†, Minji Jung‡, Dirk Wallacher§, Alexandra Franz§, Rafael Balderas-Xicohte´ncatl??, Michael Hirscher?, Sung Gu Kang#, Jitae T. Park?, In Hwan Oh*?, Hoi Ri Moon*†, and Hyunchul Oh*‡?

47、[ASAP] Catalyzed Kinetic Growth in Two-Dimensional MoS₂

Lingli Huang†‡, Quoc Huy Thi†‡, Fangyuan Zheng§?, Xin Chen†, Yee Wa Chu†, Chun-Sing Lee†, Jiong Zhao*§?, and Thuc Hue Ly*†‡

48、[ASAP] Molecular Origin of the Odd–Even Effect of Macroscopic Properties of <italic toggle="yes">n</italic>-Alkanethiolate Self-Assembled Monolayers: Bulk or Interface?

Fadwa Ben Amara‡, Eric R. Dionne‡, Sahar Kassir, Christian Pellerin*, and Antonella Badia*

49、[ASAP] Unifying Mechanism for Thiol-Induced Photoswitching and Photostability of Cyanine Dyes

Yasser Gidi†, Liam Payne†, Viktorija Glembockyte†§, Megan S. Michie‡, Martin J. Schnermann‡, and Gonzalo Cosa*†

50、[ASAP] A W/Cu Synthetic Model for the Mo/Cu Cofactor of Aerobic CODH Indicates That Biochemical CO Oxidation Requires a Frustrated Lewis Acid/Base Pair

Dibbendu Ghosh†‡, Soumen Sinhababu†‡, Bernard D. Santarsiero§, and Neal P. Mankad*†

[ASAP] Asymmetric Total Synthesis of Bufospirostenin A

Min-Jing Cheng†‡?, Li-Ping Zhong‡?, Chen-Chen Gu‡, Xu-Jiang Zhu‡, Bo Chen‡, Jun-Shan Liu§, Lei Wang*†, Wen-Cai Ye*†, and Chuang-Chuang Li*‡ 8 天前

[ASAP] An Expandable Hydrogen-Bonded Organic Framework Characterized by Three-Dimensional Electron Diffraction

Peng Cui†, Erik Svensson Grape‡, Peter R. Spackman§?, Yue Wu†, Rob Clowes†, Graeme M. Day*§?, A. Ken Inge*‡, Marc A. Little*†, and Andrew I. Cooper*†? 8 天前

[ASAP] Nanoscale Metal–Organic Framework Co-delivers TLR-7 Agonists and Anti-CD47 Antibodies to Modulate Macrophages and Orchestrate Cancer Immunotherapy

Kaiyuan Ni†‡, Taokun Luo†‡, August Culbert†, Michael Kaufmann†, Xiaomin Jiang†, and Wenbin Lin*†§ 8 天前

[ASAP] Metal-Free Direct Deoxygenative Borylation of Aldehydes and Ketones

Jianbin Li, Haining Wang, Zihang Qiu, Chia-Yu Huang, and Chao-Jun Li* 8 天前

[ASAP] Enhanced Stabilization and Easy Phase Transfer of CsPbBr₃ Perovskite Quantum Dots Promoted by High-Affinity Polyzwitterionic Ligands

Sisi Wang†, Liang Du†, Zhicheng Jin†, Yan Xin‡, and Hedi Mattoussi*† 9 天前

[ASAP] Redox Noninnocent Monoatomic Silicon(0) Complex (“Silylone”): Its One-Electron-Reduction Induces an Intramolecular One-Electron-Oxidation of Silicon(0) to Silicon(I)

Shenglai Yao†, Arseni Kostenko†, Yun Xiong†, Ales Ruzicka‡, and Matthias Driess*† 9 天前

[ASAP] Homochiral Covalent Organic Framework for Catalytic Asymmetric Synthesis of a Drug Intermediate

Hui-Chao Ma, Gong-Jun Chen*, Fang Huang, and Yu-Bin Dong* 9 天前

[ASAP] ZnMe₂-Mediated, Direct Alkylation of Electron-Deficient N-Heteroarenes with 1,1-Diborylalkanes: Scope and Mechanism

Woohyun Jo†#, Seung-yeol Baek‡§#, Chiwon Hwang†, Joon Heo‡§, Mu-Hyun Baik*§‡, and Seung Hwan Cho*† 9 天前

[ASAP] Solvation Dynamics and the Nature of Reaction Barriers and Ion-Pair Intermediates in Carbocation Reactions

Vladislav A. Roytman and Daniel A. Singleton* 9 天前

[ASAP] A Chichibabin’s Hydrocarbon-Based Molecular Cage: The Impact of Structural Rigidity on Dynamics, Stability, and Electronic Properties

Yong Ni†, Fernando Gordillo-Ga´mez‡, Miriam Pen~a Alvarez§, Zhihan Nan†, Zhengtao Li†, Shaofei Wu†, Yi Han†, Juan Casado*‡, and Jishan Wu*†? 2020-07-11

[ASAP] Excitation-Wavelength-Dependent Photoinduced Electron Transfer in a p-Conjugated Diblock Oligomer

Austin L. Jones†, Junlin Jiang†, and Kirk S. Schanze*‡ 2020-07-11

[ASAP] <italic toggle="yes">cine</italic>-Silylative Ring-Opening of a-Methyl Azacycles Enabled by the Silylium-Induced C–N Bond Cleavage

Jianbo Zhang†‡ and Sukbok Chang*†‡ 2020-07-11

[ASAP] Ordered Solvents and Ionic Liquids Can Be Harnessed for Electrostatic Catalysis

Longkun Xu†, Ekaterina I. Izgorodina*‡, and Michelle L. Coote*† 2020-07-11

[ASAP] Constructing Asymmetrical Ni-Centered {NiN₂O₄} Octahedra in Layered Metal–Organic Structures for Near-Room-Temperature Single-Phase Magnetoelectricity

Kaihui Mao†?, Jinlei Zhang†‡?, Zijing Guo†?, Lizhe Liu*†, He Ma§, Yiying Chin?, Hongji Lin?, Songsong Bao*#, Hangqing Xie†, Run Yang†, Zhaoyang Jing#, Jiancang Shen†, Guoliang Yuan§, Jian Chen?, Peiheng Wu?, and Xinglong Wu*† 2020-07-11

[ASAP] Charge Separation from an Intra-Moiety Intermediate State in the High-Performance PM6:Y6 Organic Photovoltaic Blend

Rui Wang†, Chunfeng Zhang*†, Qian Li†, Zhiguo Zhang‡, Xiaoyong Wang†, and Min Xiao†§ 2020-07-11

[ASAP] A Nonalternant Aromatic Belt: Methylene-Bridged [6]Cycloparaphenylene Synthesized from Pillar[6]arene

Yuanming Li†, Yasutomo Segawa‡§??, Akiko Yagi‡, and Kenichiro Itami*†‡§ 2020-07-10

[ASAP] Asymmetric Catalysis upon Helically Chiral Loratadine Analogues Unveils Enantiomer-Dependent Antihistamine Activity

Elizabeth A. Stone, Kara J. Cutrona, and Scott J. Miller* 2020-07-10

[ASAP] Anti-Markovnikov Hydroamination of Alkenes with Aqueous Ammonia by Metal-Loaded Titanium Oxide Photocatalyst

Soyeong Park†, Jaeyoung Jeong†, Ken-ichi Fujita†, Akira Yamamoto†‡, and Hisao Yoshida*†‡ 2020-07-10

[ASAP] Structural Properties and Catalytic Implications of the SPASM Domain Iron–Sulfur Clusters in <italic toggle="yes">Methylorubrum extorquens</italic> PqqE

Wen Zhu†, Lindsey M. Walker‡, Lizhi Tao§, Anthony T. Iavarone†, Xuetong Wei?, R. David Britt§, Sean J. Elliott*‡, and Judith P. Klinman*†?? 2020-07-10

[ASAP] Superior Transverse Piezoelectricity in a Halide Perovskite Molecular Ferroelectric Thin Film

Zhong-Xia Wang*, Hua Zhang, Fang Wang, Hao Cheng, Wen-Hui He, Yu-Hua Liu, Xue-Qin Huang, and Peng-Fei Li* 2020-07-10

[ASAP] Tetrahedral Geometry Induction of Stable Ag–Ti Nanoclusters by Flexible Trifurcate TiL₃ Metalloligand

Mei-Yan Gao†‡, Kai Wang†, Yayong Sun†, Dejing Li†, Bai-Qiao Song‡, Yassin H. Andaloussi‡, Michael J. Zaworotko‡, Jian Zhang†, and Lei Zhang*† 2020-07-09

[ASAP] Quantum Spin Liquid State in a Two-Dimensional Semiconductive Metal–Organic Framework

Yuki Misumi†, Akira Yamaguchi*‡, Zhongyue Zhang*§, Taku Matsushita?, Nobuo Wada?, Masahisa Tsuchiizu?, and Kunio Awaga*†# 2020-07-09

[ASAP] Capturing Substrate Translocation in an ABC Exporter at the Atomic Level

Hendrik Go¨ddeke and Lars V. Scha¨fer* 2020-07-09

[ASAP] Cation-Exchange Induced Precise Regulation of Single Copper Site Triggers Room-Temperature Oxidation of Benzene

Huang Zhou†8, Yafei Zhao†8, Jie Gan‡8, Jie Xu§8, Ying Wang*??, Hongwei Lv†, Shi Fang#, Zhiyuan Wang†, Ziliang Deng§, Xiaoqian Wang†, Peigen Liu†, Wenxin Guo†, Boyang Mao?, Huijuan Wang?, Tao Yao#, Xun Hong†, Shiqiang Wei#, Xuezhi Duan‡, Jun Luo§, and Yuen 2020-07-09

[ASAP] Reductive Cross-Coupling between Unactivated C(aryl)–N and C(aryl)–O Bonds by Chromium Catalysis Using a Bipyridyl Ligand

Jinghua Tang†, Fei Fan†, Xuefeng Cong†, Lixing Zhao, Meiming Luo, and Xiaoming Zeng* 2020-07-09

[ASAP] Bicelles Rich in both Sphingolipids and Cholesterol and Their Use in Studies of Membrane Proteins

James M. Hutchison†, Kuo-Chih Shih‡, Holger A. Scheidt§, Sarah M. Fantin?, Kristine F. Parson?, George A. Pantelopulos#, Haley R. Harrington?, Kathleen F. Mittendorf?, Shuo Qian?, Richard A. Stein¶, Scott E. Collier?, Melissa G. Chambers?, John Katsaras?, 2020-07-09

[ASAP] Selenomelanin: An Abiotic Selenium Analogue of Pheomelanin

Wei Cao†‡, Naneki C. McCallum†, Qing Zhe Ni§, Weiyao Li?, Hannah Boyce†, Haochuan Mao†?, Xuhao Zhou†, Hao Sun†‡, Matthew P. Thompson†‡, Claudia Battistella†‡, Michael R. Wasielewski†?, Ali Dhinojwala?, Matthew D. Shawkey*#, Michael D. Burkart*§, Zheng Wan 2020-07-09

[ASAP] Electric-Field Mediated Chemistry: Uncovering and Exploiting the Potential of (Oriented) Electric Fields to Exert Chemical Catalysis and Reaction Control

Sason Shaik*†, David Danovich†, Jyothish Joy†, Zhanfeng Wang†§, and Thijs Stuyver*†‡ 2020-07-09

[ASAP] Ethylene Selectivity in Electrocatalytic CO₂ Reduction on Cu Nanomaterials: A Crystal Phase-Dependent Study

Ye Chen†8, Zhanxi Fan‡§8, Jiong Wang?8, Chongyi Ling‡?8, Wenxin Niu†?, Zhiqi Huang‡, Guigao Liu†, Bo Chen†, Zhuangchai Lai†, Xiaozhi Liu?×, Bing Li?, Yun Zong?, Lin Gu?×, Jinlan Wang*?, Xin Wang*?, and Hua Zhang*‡§ 2020-07-08

[ASAP] Hetero<italic toggle="yes">tri</italic>metallic Precursor with 2:2:1 Metal Ratio Requiring at Least a Pentanuclear Molecular Assembly

Haixiang Han†‡, Jesse C. Carozza†, Zheng Zhou†, Yuxuan Zhang†, Zheng Wei†, Artem M. Abakumov§, Alexander S. Filatov?, Yu-Sheng Chen?, Daniel J. SantaLucia#, John F. Berry#, and Evgeny V. Dikarev*† 2020-07-08

[ASAP] Thermosalience in Macrocycle-Based Soft Crystals via Anisotropic Deformation of Disilanyl Architecture

Kenichiro Omoto†‡, Toyotaka Nakae†, Masaki Nishio†, Yoshinori Yamanoi*†, Hidetaka Kasai§, Eiji Nishibori§, Takaki Mashimo?, Tomohiro Seki?, Hajime Ito??, Kazuki Nakamura#, Norihisa Kobayashi#, Naofumi Nakayama?, Hitoshi Goto?, and Hiroshi Nishihara*† 2020-07-08

[ASAP] Synthesis of Anhydroryanodol

Kang Du†, Matthew J. Kier†, Zachary D. Stempel†, Valer Jeso†, Arnold L. Rheingold‡, and Glenn C. Micalizio*† 2020-07-08

[ASAP] Li_{<italic toggle="yes">x</italic>}NiO/Ni Heterostructure with Strong Basic Lattice Oxygen Enables Electrocatalytic Hydrogen Evolution with Pt-like Activity

Ke Lu†, Yuzi Liu‡, Fan Lin§, Isvar A. Cordova?, Siyuan Gao†, Bomin Li†, Bo Peng§, Haiping Xu†, Jacob Kaelin†, Daniel Coliz†, Cheng Wang?, Yuyan Shao#, and Yingwen Cheng*† 2020-07-08

[ASAP] Aerobic Photocatalytic H₂ Production by a [NiFe] Hydrogenase Engineered to Place a Silver Nanocluster in the Electron Relay

Liyun Zhang†, Giorgio Morello†, Stephen B. Carr*‡, and Fraser A. Armstrong*† 2020-07-08

[ASAP] Transport Phenomena: Challenges and Opportunities for Molecular Catalysis in Metal–Organic Frameworks

Ben A. Johnson, Anna M. Beiler, Brian D. McCarthy, and Sascha Ott* 2020-07-08

[ASAP] Counteranions in the Stimulation Solution Alter the Dynamics of Exocytosis Consistent with the Hofmeister Series

Xiulan He and Andrew G. Ewing* 2020-07-08

[ASAP] Spotlights on Recent <italic toggle="yes">JACS</italic> Publications

ACS Contributing Correspondents 2020-07-08

[ASAP] Cobalt/Lewis Acid Catalysis for Hydrocarbofunctionalization of Alkynes via Cooperative C–H Activation

Chang-Sheng Wang†, Sabrina Di Monaco†§, Anh Ngoc Thai†?, Md. Shafiqur Rahman†, Benjamin Piaoxiang Pang†, Chen Wang*†‡, and Naohiko Yoshikai*† 2020-07-08

[ASAP] Solid-State Phase Transformation and Self-Assembly of Amorphous Nanoparticles into Higher-Order Mineral Structures

Stanislas Von Euw*†¶, Thierry Azai¨s‡, Viacheslav Manichev§?, Guillaume Laurent‡, Ge´rard Pehau-Arnaudet?, Margarita Rivers?#, Nagarajan Murali§, Daniel J. Kelly¶, and Paul G. Falkowski*†§ 2020-07-08

[ASAP] Pd(II)-Catalyzed Enantioselective ?-C(sp³)–H Functionalizations of Free Cyclopropylmethylamines

Zhe Zhuang and Jin-Quan Yu* 2020-07-08

[ASAP] Colloidal Synthesis of Nanohelices via Bilayer Lattice Misfit

Yang Liu, Yuda Li, Soojin Jeong, Yi Wang, Jun Chen, and Xingchen Ye* 2020-07-08

[ASAP] Rational Design of Covalent Cobaloxime–Covalent Organic Framework Hybrids for Enhanced Photocatalytic Hydrogen Evolution

Kerstin Gottschling†‡§?, Go¨kcen Savasci†‡§?, Hugo Vignolo-Gonza´lez†, Sandra Schmidt‡, Philipp Mauker‡?, Tanmay Banerjee†, Petra Rovo´‡?, Christian Ochsenfeld‡†§?, and Bettina V. Lotsch*†‡§? 2020-07-07

[ASAP] Detecting Nanoscale Distribution of Protein Pairs by Proximity-Dependent Super-resolution Microscopy

Alexander H. Clowsley†?, William T. Kaufhold‡§?, Tobias Lutz†?, Anna Meletiou†, Lorenzo Di Michele§‡, and Christian Soeller*† 2020-07-07

[ASAP] Dissecting the Essential Role of Anomeric ß-Triflates in Glycosylation Reactions

Andre´s G. Santana?†, Laura Montalvillo-Jime´nez?†, Laura Di´az-Casado†, Francisco Corzana‡, Pedro Merino§, Francisco J. Can~ada?, Gonzalo Jime´nez-Ose´s?, Jesu´s Jime´nez-Barbero?#, Ana M. Go´mez†, and Juan Luis Asensio*† 2020-07-07

[ASAP] Boosting Interfacial Charge-Transfer Kinetics for Efficient Overall CO₂ Photoreduction via Rational Design of Coordination Spheres on Metal–Organic Frameworks

Zhi-Bin Fang†, Ting-Ting Liu‡, Junxue Liu§, Shengye Jin§, Xin-Ping Wu‡, Xue-Qing Gong‡, Kecheng Wang?, Qi Yin†, Tian-Fu Liu†?, Rong Cao*†?, and Hong-Cai Zhou? 2020-07-07

[ASAP] Understanding How the Rate of C–H Bond Cleavage Affects Formate Oxidation Catalysis by a Mo-Dependent Formate Dehydrogenase

William E. Robinson†§, Arnau Bassegoda‡, James N. Blaza‡?, Erwin Reisner*†, and Judy Hirst*‡ 2020-07-07

[ASAP] Investigation of the Unusual Ability of the [FeFe] Hydrogenase from <italic toggle="yes">Clostridium beijerinckii</italic> to Access an O₂-Protected State

Patrick S. Corrigan, Jonathan L. Tirsch, and Alexey Silakov* 2020-07-07

[ASAP] Bi₈Se₇: Delocalized Interlayer p-Bond Interactions Enhancing Carrier Mobility and Thermoelectric Performance near Room Temperature

Fei Jia†‡, Yong-Yi Liu†, Yi-Fan Zhang†, Xin Shu†, Ling Chen*†, and Li-Ming Wu*‡ 2020-07-07

[ASAP] Covalent vs Charge-Shift Nature of the Metal–Metal Bond in Transition Metal Complexes: A Unified Understanding

Jyothish Joy*†, David Danovich†, Martin Kaupp*‡, and Sason Shaik*† 2020-07-07

[ASAP] Probing Heterogeneous Charge Distributions at the a-Al₂O₃(0001)/H₂O Interface

Stefan M. Piontek†, Mark DelloStritto‡, Bijoya Mandal†, Tim Marshall†, Michael L. Klein‡§, and Eric Borguet*†§ 2020-07-07

[ASAP] Iridium-Catalyzed Enantioselective a-C(sp³)–H Borylation of Azacycles

Lili Chen†?, Yuhuan Yang†‡?, Luhua Liu†‡, Qian Gao†, and Senmiao Xu*†§ 2020-07-07

[ASAP] Contrasting SnTe–NaSbTe₂ and SnTe–NaBiTe₂ Thermoelectric Alloys: High Performance Facilitated by Increased Cation Vacancies and Lattice Softening

Tyler J. Slade†, Koushik Pal‡, Jann A. Grovogui‡, Trevor P. Bailey§, James Male‡, Jason F. Khoury†, Xiuquan Zhou?, Duck Young Chung?, G. Jeffrey Snyder‡, Ctirad Uher§, Vinayak P. Dravid‡, Chris Wolverton‡, and Mercouri G. Kanatzidis*†? 2020-07-07

[ASAP] Activation and Functionalization of C–C s Bonds of Alkylidene Cyclopropanes at Main Group Centers

Richard Y. Kong and Mark R. Crimmin* 2020-07-07

[ASAP] Zero-Overlap Fluorophores for Fluorescent Studies at Any Concentration

Ayan Dhara, Tumpa Sadhukhan, Edward G. Sheetz, Andrew H. Olsson, Krishnan Raghavachari, and Amar H. Flood* 2020-07-07

[ASAP] Frequency-Agile Low-Temperature Solution-Processed Alumina Dielectrics for Inorganic and Organic Electronics Enhanced by Fluoride Doping

Xinming Zhuang†‡, Sawankumar Patel§, Chi Zhang?, Binghao Wang‡, Yao Chen‡, Haoyu Liu§, Vinayak P. Dravid*?, Junsheng Yu*†, Yan-Yan Hu*?§, Wei Huang*‡, Antonio Facchetti*‡#, and Tobin J. Marks*‡ 2020-07-07

[ASAP] Helical Carbenium Ion: A Versatile Organic Photoredox Catalyst for Red-Light-Mediated Reactions

Liangyong Mei, Jose´ M. Veleta, and Thomas L. Gianetti* 2020-07-06

[ASAP] Modular Tuning of Electrophilic Reactivity of Iridium Nitrenoids for the Intermolecular Selective a-Amidation of ß-Keto Esters

Minhan Lee†‡, Hoimin Jung†‡, Dongwook Kim‡†, Jung-Woo Park*‡†, and Sukbok Chang*‡† 2020-07-04

[ASAP] Water Is the Oxygen Source for Methanol Produced in Partial Oxidation of Methane in a Flow Reactor over Cu-SSZ-13

Aibolat Koishybay and Daniel F. Shantz* 2020-07-04

[ASAP] HIO_{<italic toggle="yes">x</italic>}–IONO₂ Dynamics at the Air–Water Interface: Revealing the Existence of a Halogen Bond at the Atmospheric Aerosol Surface

Manoj Kumar†, Tarek Trabelsi†, Juan Carlos Go´mez Marti´n‡, Alfonso Saiz-Lopez§, and Joseph S. Francisco*† 2020-07-04

[ASAP] Photochemical Phase Transitions Enable Coharvesting of Photon Energy and Ambient Heat for Energetic Molecular Solar Thermal Batteries That Upgrade Thermal Energy

Zhao-Yang Zhang†, Yixin He†, Zhihang Wang‡, Jiale Xu§, Mingchen Xie†, Peng Tao§, Deyang Ji?, Kasper Moth-Poulsen*‡, and Tao Li*† 2020-07-04

[ASAP] Large-Cavity Coronoids with Different Inner and Outer Edge Structures

Marco Di Giovannantonio*†?, Xuelin Yao‡?, Kristjan Eimre†?, Jose´ I. Urgel†, Pascal Ruffieux†, Carlo A. Pignedoli*†, Klaus Mu¨llen*‡§, Roman Fasel†?, and Akimitsu Narita*‡? 2020-07-03

[ASAP] Regioselective and Stereospecific Rhodium-Catalyzed Allylic Cyanomethylation with an Acetonitrile Equivalent: Construction of Acyclic ß-Quaternary Stereogenic Nitriles

Mai-Jan Tom† and P. Andrew Evans*†‡ 2020-07-03

[ASAP] Palladium-Catalyzed <italic toggle="yes">meta</italic>-C–H Allylation of Arenes: A Unique Combination of a Pyrimidine-Based Template and Hexafluoroisopropanol

Sukdev Bag†, Surya K†, Arup Mondal†, Ramasamy Jayarajan†, Uttam Dutta†, Sandip Porey†, Raghavan B. Sunoj*†, and Debabrata Maiti*†‡ 2020-07-03

[ASAP] Arylphosphonate-Directed Ortho C–H Borylation: Rapid Entry into Highly-Substituted Phosphoarenes

Feiyang Xu†‡, Olivia M. Duke†, Daniel Rojas†, Hanka M. Eichelberger†‡, Raphael S. Kim†, Timothy B. Clark*‡, and Donald A. Watson*† 2020-07-03

[ASAP] Bottom-up Synthesis of Nitrogen-Doped Porous Graphene Nanoribbons

Re´my Pawlak*†#, Xunshan Liu‡?#, Silviya Ninova‡, Philipp D’Astolfo†, Carl Drechsel†, Sara Sangtarash§, Robert Ha¨ner‡, Silvio Decurtins‡, Hatef Sadeghi§, Colin J. Lambert?, Ulrich Aschauer‡, Shi-Xia Liu*‡, and Ernst Meyer*† 2020-07-03

[ASAP] Transmembrane Epitope Delivery by Passive Protein Threading through the Pores of the OmpF Porin Trimer

Sejeong Lee†, Nicholas G. Housden‡, Sandra A. Ionescu†, Matthew H. Zimmer†§, Renata Kaminska‡, Colin Kleanthous‡, and Hagan Bayley*† 2020-07-03

[ASAP] Fast Proton Transfer and Hydrogen Evolution Reactivity Mediated by [Co₁₃C₂(CO)₂₄]^4–

Cody R. Carr, Atefeh Taheri, and Louise A. Berben* 2020-07-03

[ASAP] Dynamic Evolution of Solid–Liquid Electrochemical Interfaces over Single-Atom Active Sites

Hui Su†, Wanlin Zhou†, Hui Zhang†, Wu Zhou‡, Xu Zhao†, Yuanli Li†, Meihuan Liu†, Weiren Cheng*†, and Qinghua Liu*† 2020-07-03

[ASAP] Isothermal Titration Calorimetry to Explore the Parameter Space of Organophosphorus Agrochemical Adsorption in MOFs

Riki J. Drout†, Satoshi Kato†, Haoyuan Chen‡, Florencia A. Son†, Ken-ichi Otake†$, Timur Islamoglu†, Randall Q. Snurr‡, and Omar K. Farha*†‡ 2020-07-03

[ASAP] Microporous Hydrogen-Bonded Organic Framework for Highly Efficient Turn-Up Fluorescent Sensing of Aniline

Bin Wang†‡#, Ru He‡§#, Lin-Hua Xie?, Zu-Jin Lin‡, Xin Zhang‡, Jing Wang‡, Hongliang Huang?, Zhangjing Zhang*†, Kirk S. Schanze‡, Jian Zhang?, Shengchang Xiang†, and Banglin Chen*‡ 2020-07-03

[ASAP] Stereoretentive Ring-Opening Metathesis Polymerization to Access All-<italic toggle="yes">cis</italic> Poly(<italic toggle="yes">p</italic>-phenylenevinylene)s with Living Characteristics

Ting-Wei Hsu†, Cheoljae Kim†‡, and Quentin Michaudel* 2020-07-03

[ASAP] Multimodal Structure Solution with ¹⁹F NMR Crystallography of Spin Singlet Molybdenum Oxyfluorides

Fenghua Ding†?, Kent J. Griffith†?, Can P. Koc¸er§, Richard J. Saballos‡, Yiran Wang†, Chi Zhang‡, Matthew L. Nisbet†, Andrew J. Morris*?, James M. Rondinelli*‡, and Kenneth R. Poeppelmeier*† 2020-07-03

[ASAP] A Concise, Enantiospecific Total Synthesis of Chilocorine C Fueled by a Reductive Cyclization/Mannich Reaction Cascade

Vladislav G. Lisnyak and Scott A. Snyder* 2020-07-03

[ASAP] Photoresponsive Dithienylethene-Containing Tris(8-hydroxyquinolinato)aluminum(III) Complexes with Photocontrollable Electron-Transporting Properties for Solution-Processable Optical and Organic Resistive Memory Devices

Cheok-Lam Wong, Maggie Ng, Eugene Yau-Hin Hong, Yi-Chun Wong, Mei-Yee Chan, and Vivian Wing-Wah Yam* 2020-07-03

[ASAP] Visible-Light-Enabled <italic toggle="yes">Ortho</italic>-Selective Aminopyridylation of Alkenes with <italic toggle="yes">N</italic>-Aminopyridinium Ylides

Yonghoon Moon†‡, Wooseok Lee†‡, and Sungwoo Hong*†‡ 2020-07-03

[ASAP] Structure, Spectroscopy, and Reactivity of a Mononuclear Copper Hydroxide Complex in Three Molecular Oxidation States

Tong Wu†, Samantha N. MacMillan§, Khashayar Rajabimoghadam†, Maxime A. Siegler#, Kyle M. Lancaster*§, and Isaac Garcia-Bosch*† 2020-07-02

[ASAP] Enantioselective Diarylcarbene Insertion into Si–H Bonds Induced by Electronic Properties of the Carbenes

Liang-Liang Yang†, Declan Evans‡, Bin Xu†, Wen-Tao Li†, Mao-Lin Li†, Shou-Fei Zhu*†, K. N. Houk*‡, and Qi-Lin Zhou*† 2020-07-02

[ASAP] A Stable Ferryl Porphyrin at the Active Site of Y463M BthA

Kimberly Rizzolo†#, Andrew C. Weitz†‡#, Steven E. Cohen§, Catherine L. Drennan§??, Michael P. Hendrich‡, and Sean J. Elliott*† 2020-07-02

[ASAP] Discovery of a Potent and Selective Covalent Inhibitor and Activity-Based Probe for the Deubiquitylating Enzyme UCHL1, with Antifibrotic Activity

Nattawadee Panyain†, Aure´lien Godinat†, Thomas Lanyon-Hogg†, Sofi´a Lachiondo-Ortega†?, Edward J. Will†, Christelle Soudy‡, Milon Mondal†, Katie Mason§, Sarah Elkhalifa§, Lisa M. Smith§, Jeanine A. Harrigan§, and Edward W. Tate*†‡ 2020-07-02

[ASAP] Fluorescent Membrane Tension Probes for Super-Resolution Microscopy: Combining Mechanosensitive Cascade Switching with Dynamic-Covalent Ketone Chemistry

Jose´ Garci´a-Calvo, Jimmy Maillard, Ina Fureraj, Karolina Strakova, Adai Colom, Vincent Mercier, Aurelien Roux, Eric Vauthey, Naomi Sakai, Alexandre Fu¨rstenberg*, and Stefan Matile* 2020-07-02

[ASAP] Optically Active Flavaglines-Inspired Molecules by a Palladium-Catalyzed Decarboxylative Dearomative Asymmetric Allylic Alkylation

Meng-Yue Cao†?§, Bin-Jie Ma†?, Zhi-Qi Lao†?, Hongliang Wang§, Jing Wang†?, Juan Liu‡, Kuan Xing†?, Yu-Hao Huang†?, Kang-Ji Gan†?§, Wei Gao‡, Huaimin Wang†?, Xin Hong§, and Hai-Hua Lu*†?‡§ 2020-07-02

[ASAP] Versatile Cp*Co(III)(LX) Catalyst System for Selective Intramolecular C–H Amidation Reactions

Jia Lee†‡§, Jeonghyo Lee†‡§, Hoimin Jung†‡, Dongwook Kim‡†, Juhyeon Park†‡, and Sukbok Chang*‡† 2020-07-02

[ASAP] <italic toggle="yes">o</italic>-Carborane-Based and Atomically Precise Metal Clusters as Hypergolic Materials

Qian-You Wang†#, Jie Wang†#, Shan Wang†, Zhao-Yang Wang†, Man Cao†, Chun-Lin He§, Jun-Qing Yang‡, Shuang-Quan Zang*†, and Thomas C. W. Mak†? 2020-07-02

[ASAP] Catalytic Allylation of Aldehydes Using Unactivated Alkenes

Shun Tanabe, Harunobu Mitsunuma*, and Motomu Kanai* 2020-07-01

[ASAP] Regioselective, Photocatalytic a-Functionalization of Amines

Lingying Leng†, Yue Fu‡, Peng Liu*‡, and Joseph M. Ready*† 2020-07-01

[ASAP] Enantioselective Copper-Catalyzed Alkynylation of Benzylic C–H Bonds via Radical Relay

Liang Fu†?, Zhihan Zhang‡?, Pinhong Chen†, Zhenyang Lin*‡, and Guosheng Liu*†§ 2020-07-01

[ASAP] The Soft Molecular Polycrystalline Ferroelectric Realized by the Fluorination Effect

Yongfa Xie†, Yong Ai†, Yu-Ling Zeng†, Wen-Hui He†, Xue-Qin Huang†, Da-Wei Fu*‡, Ji-Xing Gao‡, Xiao-Gang Chen‡, and Yuan-Yuan Tang*† 2020-07-01

[ASAP] Correction to “A Heterotrimeric Dehydrogenase Complex Functions with 2 Distinct YcaO Proteins to Install 5 Azole Heterocycles in 35-Membered Sulfomycin Thiopeptides”

Yanan Du, Yanping Qiu, Xiang Meng, Junyin Feng, Jiang Tao, and Wen Liu* 2020-07-01

[ASAP] Shape Matching in Superatom Chemistry and Assembly

Jingjing Yang†, Feifan Wang†, Jake C. Russell†, Taylor J. Hochuli†, Xavier Roy†, Michael L. Steigerwald†, Xiaoyang Zhu†, Daniel W. Paley*‡, and Colin Nuckolls*† 2020-07-01

[ASAP] Silver Double Nanorings with Circular Hot Zone

Sungjae Yoo†, Junghwa Lee†, Jeongwon Kim†, Jae-Myoung Kim‡, MohammadNavid Haddadnezhad†, Sungwoo Lee†, Sungwoo Choi§, Doojae Park§, Jwa-Min Nam‡, and Sungho Park*† 2020-07-01

[ASAP] Ferroelectric Instability Induced Ultralow Thermal Conductivity and High Thermoelectric Performance in Rhombohedral <italic toggle="yes">p</italic>-Type GeSe Crystal

Debattam Sarkar†, Tanmoy Ghosh†, Subhajit Roychowdhury†, Raagya Arora‡, Sandra Sajan?, Goutam Sheet?, Umesh V. Waghmare‡§?, and Kanishka Biswas*†§? 2020-07-01

[ASAP] Structural Oscillation Revealed in Gold Nanoparticles

Nan Xia†‡?, Jinyun Yuan§?, Lingwen Liao†‡, Wenhao Zhang†‡, Jin Li?, Haiteng Deng?, Jinlong Yang*§, and Zhikun Wu*†‡ 2020-07-01

[ASAP] Correction to “Electrochemically Determined O–H Bond Dissociation Free Energies of NiO Electrodes Predict Proton-Coupled Electron Transfer Reactivity”

Catherine F. Wise and James M. Mayer* 2020-07-01

[ASAP] Correction to “Protein–Protein Cross-Coupling via Palladium–Protein Oxidative Addition Complexes from Cysteine Residues”

Heemal H. Dhanjee, Azin Saebi, Ivan Buslov, Alexander R. Loftis, Stephen L. Buchwald*, and Bradley L. Pentelute* 2020-07-01

[ASAP] How Water in Aliphatic Solvents Directs the Interference of Chemical Reactivity in a Supramolecular System

Mathijs F. J. Mabesoone, Gijs M. ter Huurne, Anja R. A. Palmans, and E. W. Meijer* 2020-07-01

[ASAP] Dynamic Reoxidation/Reduction-Driven Atomic Interdiffusion for Highly Selective CO₂ Reduction toward Methane

Chia-Jui Chang§†, Sheng-Chih Lin§†, Hsiao-Chien Chen†, Jiali Wang†, Kai Jen Zheng†, Yanping Zhu†, and Hao Ming Chen*†‡ 2020-07-01

[ASAP] Sense-and-Release Logic-Gated Molecular Network Responding to Dimeric Cell Surface Proteins

Simona Angerani and Nicolas Winssinger* 2020-07-01

[ASAP] Interfacial Vibrational Dynamics of Ice I_h and Liquid Water

Prerna Sudera†, Jene´e D. Cyran†§, Malte Deiseroth†, Ellen H. G. Backus*†‡, and Mischa Bonn*† 2020-07-01

[ASAP] Scalable Bifunctional Organoboron Catalysts for Copolymerization of CO₂ and Epoxides with Unprecedented Efficiency

Guan-Wen Yang, Yao-Yao Zhang, Rui Xie, and Guang-Peng Wu* 2020-07-01

[ASAP] Continuous Electrical Conductivity Variation in M₃(Hexaiminotriphenylene)₂ (M = Co, Ni, Cu) MOF Alloys

Tianyang Chen†, Jin-Hu Dou†, Luming Yang†, Chenyue Sun†, Nicole J. Libretto‡, Grigorii Skorupskii†, Jeffrey T. Miller‡, and Mircea Dinca?*† 2020-07-01

[ASAP] Ultrasensitive Detection of Attomolar Protein Concentrations by Dropcast Single Molecule Assays

Connie Wu†‡, Padric M. Garden†‡, and David R. Walt*†‡ 2020-07-01

[ASAP] Stereoselective Synthesis of <italic toggle="yes">Cis</italic>- and <italic toggle="yes">Trans</italic>-Tetrasubstituted Vinyl Silanes Using a Silyl-Heck Strategy and Hiyama Conditions for Their Cross-Coupling

Michael F. Wisthoff‡, Sarah B. Pawley‡, Andrew P. Cinderella, and Donald A. Watson* 2020-07-01

[ASAP] Potent and Prolonged Innate Immune Activation by Enzyme-Responsive Imidazoquinoline TLR7/8 Agonist Prodrug Vesicles

Bi Wang†, Simon Van Herck‡, Yong Chen‡, Xiangyang Bai†, Zifu Zhong§, Kim Deswarte?, Bart N. Lambrecht??, Niek N. Sanders§, Stefan Lienenklaus@, Hans W. Scheeren†, Sunil A. David#, Fabian Kiessling†, Twan Lammers*†??, Bruno G. De Geest*‡, and Yang Shi*† 2020-07-01

[ASAP] Quantification of Multivalent Interactions between Sialic Acid and Influenza A Virus Spike Proteins by Single-Molecule Force Spectroscopy

Jose Luis Cuellar-Camacho*†, Sumati Bhatia*†, Valentin Reiter-Scherer‡, Daniel Lauster†§, Susanne Liese?, Ju¨rgen P. Rabe‡, Andreas Herrmann§, and Rainer Haag† 2020-07-01

[ASAP] Mechanism of Oxygen Evolution Catalyzed by Cobalt Oxyhydroxide: Cobalt Superoxide Species as a Key Intermediate and Dioxygen Release as a Rate-Determining Step

Aliki Moysiadou†‡, Seunghwa Lee†‡, Chia-Shuo Hsu§, Hao Ming Chen§, and Xile Hu*† 2020-07-01

[ASAP] Electrochemical Strategy for Hydrazine Synthesis: Development and Overpotential Analysis of Methods for Oxidative N–N Coupling of an Ammonia Surrogate

Fei Wang, James B. Gerken, Desiree M. Bates, Yeon Jung Kim, and Shannon S. Stahl* 2020-07-01

[ASAP] Aptamers as Versatile Molecular Tools for Antibody Production Monitoring and Quality Control

Kaiming Chen†, Jie Zhou‡, Zhentao Shao†, Jia Liu†, Jia Song†, Ruowen Wang*†, Juan Li*†‡, and Weihong Tan*†§ 2020-07-01

[ASAP] Supramolecular Exchange among Assemblies of Opposite Charge Leads to Hierarchical Structures

James R. Wester†#, Jacob A. Lewis†‡#, Ronit Freeman†#?, Hiroaki Sai†§, Liam C. Palmer†?, Stephen E. Henrich†‡, and Samuel I. Stupp*†‡§?? 2020-07-01

[ASAP] Shallow Distance Dependence for Proton-Coupled Tyrosine Oxidation in Oligoproline Peptides

Brian Koronkiewicz*‡, John Swierk†, Kevin Regan, and James M. Mayer* 2020-07-01

[ASAP] <italic toggle="yes">Operando</italic> Identification of the Dynamic Behavior of Oxygen Vacancy-Rich Co₃O₄ for Oxygen Evolution Reaction

Zhaohui Xiao†?, Yu-Cheng Huang‡?, Chung-Li Dong‡?, Chao Xie†, Zhijuan Liu†, Shiqian Du†, Wei Chen†, Dafeng Yan†, Li Tao†, Zhiwen Shu§, Guanhua Zhang§, Huigao Duan§, Yanyong Wang†, Yuqin Zou†, Ru Chen†, and Shuangyin Wang*† 2020-07-01

[ASAP] Correction to “Observation of Resonant Quantum Magnetoelectric Effect in a Multiferroic Metal–Organic Framework”

Ying Tian, Shipeng Shen, Junzhuang Cong, Liqin Yan, Shouguo Wang, and Young Sun* 2020-07-01

[ASAP] Spotlights on Recent <italic toggle="yes">JACS</italic> Publications

ACS Contributing Correspondents 2020-07-01

[ASAP] Shape Complementarity Modulated Self-Assembly of Nanoring and Nanosphere Hetero-nanostructures

Na Li†‡, Fan Wu?, Zihong Han†‡, Xiaofeng Wang†‡, Yi Liu§, Chenglin Yi¶, Shunsheng Ye¶, Guowei Lu?, Li Yu?, Zhihong Nie*¶, and Baoquan Ding*†‡ 2020-07-01

[ASAP] Ion-Assisted Resonant Injection and Charge Storage in Carbon-Based Molecular Junctions

Mustafa Supur, Shailendra K. Saxena, and Richard L. McCreery* 2020-07-01

[ASAP] Employing Conductive Metal–Organic Frameworks for Voltammetric Detection of Neurochemicals

Michael Ko†, Lukasz Mendecki†, Aileen M. Eagleton, Claudia G. Durbin, Robert M. Stolz, Zheng Meng, and Katherine A. Mirica* 2020-07-01

[ASAP] Visible-Light-Driven Nitrogen Fixation Catalyzed by Bi₅O₇Br Nanostructures: Enhanced Performance by Oxygen Vacancies

Peishen Li†, Ziang Zhou†, Qiang Wang*†, Ming Guo†, Shaowei Chen*‡, Jingxiang Low§, Ran Long§, Wen Liu*?, Peiren Ding†, Yunyun Wu†, and Yujie Xiong*§ 2020-07-01

[ASAP] Supramolecular Fullerene Tetramers Concocted with Porphyrin Boxes Enable Efficient Charge Separation and Delocalization

Xiujun Yu†?, Bingzhe Wang??, Younghoon Kim†‡?, Jiyong Park?#, Samrat Ghosh?, Barun Dhara†, Rahul Dev Mukhopadhyay†, Jaehyoung Koo†‡, Ikjin Kim†§, Seungha Kim#?, In-Chul Hwang*†, Shu Seki*?, Dirk M. Guldi*?, Mu-Hyun Baik*?#, and Kimoon Kim*†‡ 2020-07-01

[ASAP] Stereoselective Functionalization of Racemic Cyclopropylzinc Reagents via Enantiodivergent Relay Coupling

Lun An†#, Fei-Fei Tong†#, Shu Zhang‡, and Xingang Zhang*† 2020-06-27

[ASAP] Cross-Electrophile Coupling of Unactivated Alkyl Chlorides

Holt A. Sakai†, Wei Liu†, Chi “Chip” Le, and David W. C. MacMillan* 2020-06-27

[ASAP] Vinylene-Bridged Two-Dimensional Covalent Organic Frameworks via Knoevenagel Condensation of Tricyanomesitylene

Shuai Bi#, Palani Thiruvengadam#, Shice Wei, Wenbei Zhang, Fan Zhang, Lusha Gao, Junsong Xu, Dongqing Wu, Jie-Sheng Chen, and Fan Zhang* 2020-06-27

[ASAP] Alignment and Photopolymerization of Hexa-<italic toggle="yes">peri</italic>-hexabenzocoronene Derivatives Carrying Diacetylenic Side Chains for Charge-Transporting Application

Fang-Ju Lin†, Chih-Wen Yang‡, Hsiu-Hui Chen*§, and Yu-Tai Tao*† 2020-06-27

[ASAP] Supramolecular Chemistry-Based One-Pot High-Efficiency Separation of Solubilizer-Free Pure Semiconducting Single-Walled Carbon Nanotubes: Molecular Strategy and Mechanism

Naotoshi Nakashima*†, Masashi Fukuzawa‡, Kanako Nishimura‡, Tsuyohiko Fujigaya‡, Yuichi Kato‡§, and Aleksandar Staykov† 2020-06-27

[ASAP] Highly Selective ß-Mannosylations and ß-Rhamnosylations Catalyzed by Bis-thiourea

Qiuhan Li, Samuel M. Levi†, and Eric N. Jacobsen* 2020-06-27

[ASAP] Catalytic Hydrogenolysis of Aryl C–F Bonds Using a Bimetallic Rhodium–Indium Complex

James T. Moore† and Connie C. Lu*† 2020-06-26

[ASAP] High Proton Conductivity in Ba₅Er₂Al₂ZrO₁₃, a Hexagonal Perovskite-Related Oxide with Intrinsically Oxygen-Deficient Layers

Taito Murakami†, James R. Hester‡, and Masatomo Yashima*† 2020-06-26

[ASAP] Electrochemical Switching of a Fluorescent Molecular Rotor Embedded within a Bistable Rotaxane

Yilei Wu†, Marco Frasconi*‡, Wei-Guang Liu§, Ryan M. Young†, William A. Goddard III§, Michael R. Wasielewski*†?, and J. Fraser Stoddart*†?# 2020-06-26

[ASAP] Hydrogen Migration-Triggered Diradicaloid Singlet-Fission Switch

Qing Li†‡§, Yu-He Kan*‡†, Hong-Liang Xu*†, and Zhong-Min Su*†? 2020-06-26

[ASAP] Elucidating the Weakly Reversible Cs–Pb–Br Perovskite Nanocrystal Reaction Network with High-Throughput Maps and Transformations

Jakob C. Dahl†§?, Xingzhi Wang†§, Xiao Huang†, Emory M. Chan?, and A. Paul Alivisatos*†‡§? 2020-06-25

[ASAP] “Colloid–Atom Duality” in the Assembly Dynamics of Concave Gold Nanoarrows

Chang Liu†, Zihao Ou†, Fucheng Guo?, Binbin Luo†, Wenxiang Chen†, Limin Qi*?, and Qian Chen*†‡§? 2020-06-25

[ASAP] A Peroxodiiron(III/III) Intermediate Mediating Both <italic toggle="yes">N</italic>-Hydroxylation Steps in Biosynthesis of the <italic toggle="yes">N</italic>-Nitrosourea Pharmacophore of Streptozotocin by the Multi-domain M

Molly J. McBride†, Debangsu Sil†, Tai L. Ng§#, Anne Marie Crooke§, Grace E. Kenney§, Christina R. Tysoe†, Bo Zhang†‡, Emily P. Balskus*§, Amie K. Boal*†?, Carsten Krebs*†?, and J. Martin Bollinger, Jr.*†? 2020-06-25

[ASAP] Lead-Free Cs₄CuSb₂Cl₁₂ Layered Double Perovskite Nanocrystals

Tong Cai†, Wenwu Shi†‡, Sooyeon Hwang§, Kanishka Kobbekaduwa?, Yasutaka Nagaoka†, Hanjun Yang†, Katie Hills-Kimball†, Hua Zhu†, Junyu Wang†, Zhiguo Wang‡, Yuzi Liu?, Dong Su§, Jianbo Gao?, and Ou Chen*† 2020-06-25

[ASAP] Donor–Acceptor Dihydropyrenes Switchable with Near-Infrared Light

Kristin Klaue†?, Wenjie Han†?, Pauline Liesfeld†, Fabian Berger†, Yves Garmshausen†, and Stefan Hecht*†‡§ 2020-06-25

[ASAP] Enantioselective Si–H Insertion Reactions of Diarylcarbenes for the Synthesis of Silicon-Stereogenic Silanes

Jake R. Jagannathan, James C. Fettinger, Jared T. Shaw*, and Annaliese K. Franz* 2020-06-25

[ASAP] Correction to “Tailoring Passivation Molecular Structures for Extremely Small Open-Circuit Voltage Loss in Perovskite Solar Cells”

Shuang Yang, Jun Dai, Zhenhua Yu, Yuchuan Shao, Yu Zhou, Xun Xiao, Xiao Cheng Zeng, and Jinsong Huang* 2020-06-25

[ASAP] Magnesiation of Aryl Fluorides Catalyzed by a Rhodium–Aluminum Complex

Ikuya Fujii†§, Kazuhiko Semba†§, Qiao-Zhi Li‡, Shigeyoshi Sakaki*‡, and Yoshiaki Nakao*† 2020-06-25

[ASAP] Effects of Noncovalent Interactions on High-Spin Fe(IV)–Oxido Complexes

Victoria F. Oswald†, Justin L. Lee†, Saborni Biswas‡, Andrew C. Weitz‡, Kaustuv Mittra§, Ruixi Fan‡, Jikun Li‡, Jiyong Zhao?, Michael Y. Hu?, Esen E. Alp?, Emile L. Bominaar‡, Yisong Guo‡, Michael T. Green†§, Michael P. Hendrich*‡, and A. S. Borovik*† 2020-06-25

[ASAP] ROY Reclaims Its Crown: New Ways To Increase Polymorphic Diversity

Alexandre Le´vesque, Thierry Maris, and James D. Wuest* 2020-06-25

[ASAP] Superoxide-Based K–O₂ Batteries: Highly Reversible Oxygen Redox Solves Challenges in Air Electrodes

Lei Qin, Luke Schkeryantz, Jingfeng Zheng, Neng Xiao, and Yiying Wu* 2020-06-24

[ASAP] Stable and Efficient Single-Atom Zn Catalyst for CO₂ Reduction to CH₄

Lili Han†‡#, Shoujie Song†#, Mingjie Liu§#, Siyu Yao?, Zhixiu Liang?, Hao Cheng‡, Zhouhong Ren†, Wei Liu†, Ruoqian Lin?, Gaocan Qi?, Xijun Liu*†, Qin Wu*§, Jun Luo*†, and Huolin L. Xin*‡ 2020-06-24

[ASAP] On the Coupling of Electron Transfer to Proton Transfer at Electrified Interfaces

Aimin Ge†?, Georg Kastlunger‡?, Jinhui Meng†, Per Lindgren‡, Jia Song†, Qiliang Liu†, Alexander Zaslavsky‡, Tianquan Lian*†, and Andrew A. Peterson*‡ 2020-06-24

[ASAP] Selectivity via Cooperativity: Preferential Stabilization of the p65/14-3-3 Interaction with Semisynthetic Natural Products

Madita Wolter†, Pim de Vink†, Joa~o Filipe Neves‡§, Sonja Srdanovic´?, Yusuke Higuchi?, Nobuo Kato?, Andrew Wilson?#, Isabelle Landrieu‡§, Luc Brunsveld†, and Christian Ottmann*†¶ 2020-06-24

[ASAP] Total Synthesis Provides Strong Evidence: Xestocyclamine A is the Enantiomer of Ingenamine

Zhanchao Meng and Alois Fu¨rstner* 2020-06-24

[ASAP] Discovery and Total Synthesis of a Bis(cyclotryptamine) Alkaloid Bearing the Elusive Piperidinoindoline Scaffold

Jordan J. Dotson, J. Logan Bachman, Miguel A. Garcia-Garibay*, and Neil K. Garg* 2020-06-24

[ASAP] Spotlights on Recent <italic toggle="yes">JACS</italic> Publications

ACS Contributing Correspondents 2020-06-24

[ASAP] Probing Electric Field Distributions in the Double Layer of a Single-Crystal Electrode with Angstrom Spatial Resolution using Raman Spectroscopy

Bao-Ying Wen†, Jia-Sheng Lin†, Yue-Jiao Zhang†, Petar M. Radjenovic†, Xia-Guang Zhang*‡, Zhong-Qun Tian†, and Jian-Feng Li*† 2020-06-24

[ASAP] Synthesis of (-)-Picrotoxinin by Late-Stage Strong Bond Activation

Steven W. M. Crossley†§, Guanghu Tong§, Michael J. Lambrecht‡, Hannah E. Burdge, and Ryan A. Shenvi* 2020-06-24

[ASAP] DNA-Based Nanostructures for Live-Cell Analysis

Sasha B. Ebrahimi†?, Devleena Samanta‡?, and Chad A. Mirkin*‡†? 2020-06-24

[ASAP] Bismuth-Catalyzed Oxidative Coupling of Arylboronic Acids with Triflate and Nonaflate Salts

Oriol Planas, Vytautas Peciukenas, and Josep Cornella* 2020-06-24

[ASAP] Dinaphthothiepine Bisimide and Its Sulfoxide: Soluble Precursors for Perylene Bisimide

Sakiho Hayakawa†, Kyohei Matsuo‡, Hiroko Yamada*‡, Norihito Fukui*†, and Hiroshi Shinokubo*† 2020-06-24

[ASAP] Site-Selective Copper-Catalyzed Azidation of Benzylic C–H Bonds

Sung-Eun Suh†, Si-Jie Chen†, Mukunda Mandal‡, Ilia A. Guzei†, Christopher J. Cramer‡, and Shannon S. Stahl*† 2020-06-24

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